Gin Wigmore is the artist in the Skyfall Heineken commercial. The song is called Man Like That. It is from her 2011 album Gravel & Wine.
Having James Bond swap out his vodka martini for a Heineken cost the beer company a whopping $44 million dollars! He also appeared in the movie drinking a Heineken. Due to financial problems that MGM was having, Daniel Craig said the movie would not have been completed if it were not for the Heineken deal.
Skyfall is scheduled to be released on DVD on February 12, 2013.