No. Villanova is not an Ivy League school.
Ivy League schools consist of the following universities:
Brown University
University
Cornell University
Dartmouth University
Harvard University
Princeton University
University of Pennsylvania
Yale University
These are some of the most selective colleges in the United States and the also rank among the country's top private universities.
Each one of these universities has top-ranked academics and award-winning faculty. The members of the Ivy League can also boast of beautiful and historic campuses.
Learn more about each university including its costs, financial aid, and SAT/ACT data at collegeapps.about.com.
Of interest, WTVR.com features how this teenager got into 8 Ivy Leagues and 13 other schools.